20. - 23.05. 2012 Ouro Minas Palace Hotel Av. Cristiano Machado, 4001 Belo Horizonte, Minas Gerais, Brazil www.abmbrasil.com.br
Aluminium 2012
9th World Trade Fair & Conference 09.-11. October 2012 Düsseldorf, Germany www.aluminium-messe.com
We exhibit: Hall 9, Exhibition booth 9H02
New factory for pre-fabricated refractory components in Dülmen
Refratechnik expands its activities in the field of preshaped refractories, and is starting operations in a new factory for pre-fabricated refractory components in Dülmen, North Rhine-Westphalia, Germany.
Using the high-grade refractory concrete produced in our Bendorf factory, complex and large-sized components will be manufactured at the new site.
Production is based on pioneering standards and in accordance with our aims of best possible environmental compatibility and sustainability. Already during the planning phase, all the structures required for production were also assessed and shaped according to ecological aspects.
Bendorf factory uses 100% green energy for production
Since June 1, 2011 all of the electric power used in Refratechnik Steel GmbH`s factory in Bendorf comes from hydroelectric sources. This is ensured by official proof of origin certificates from the utilities company. In this way, regenerative energy contributes toward a favourable carbon footprint for the Bendorf technology site.
Update 1.1 available
New: Refratechnik App
The first ever app for refractory solutions, showing and illustrate refractory technology and applications for the Steel- and Non-ferrous-industry. The app illustrates clearly, using 2D- and 3D-animations, how kilns and ladles in the Steel- and Non-ferrous-industry are supplied with refractories to allow the production of steel and non-ferrous metals. iTunes Preview
CERAMAC® – the smart solution for the longest service life without emissions
In the beginning, the original goal in developing CERAMAC was to make it easier to meet environmental regulations and to improve the service life. In the lining concepts, the pre-fired material reduces the smoke emissions and the release of particles while also improving mechanical properties.
Let´s talk about your goals. We will find the right way.
CERAMAC® – low emissions and high-performance lifetime Over the last few decades, magnesia carbon bricks have become the standard refractory material for many areas in steel production. Compared to other ceramic refractory products, the magnesia carbon products have taken on a special role.
CERAMAC® increases the service life of the ladle
Stability ranges in the MgO+C system
Microstructure of a CERAMAC® brick: Magnesia or periclase (light gray) and graphite (dark gray)
At the time of delivery and installation into the respective furnace, all carbon-bonded products are in an “unfinished” state. The actual properties in the magnesia carbon bricks do not become active until they are used in steel works and come into contact with liquid steel. Due to the high temperatures during the application, the bricks go through a process in which many application-related properties change.
All mechanical and physical properties in the magnesia carbon bricks depend on the thermal history, meaning their working temperature. In the furnaces, temperature profiles develop from the hot face to the cold side of the lining. Accordingly, the properties of the magnesia carbon wear lining change constantly, from pre-heating until the last charging in the furnace, which causes inhomogeneous properties inside the bricks to be distributed. Different emissions can be released particularly during the pre-heating phase of a furnace lined with magnesia carbon bricks. In contrast to the pitch-bonded products, REFRAFLEX® bonded bricks produce non-poisonous emissions, though they are frequently perceived as unpleasant due to the smoke and odors they emit. After the successful introduction of the REFRAFLEX® bonding system, Refratechnik developed thermally treated MgO-C-bricks: The CERAMAC® product line.
Pre-firing, which occurs in the range of the working temperatures, causes a partial ceramic bond to form that endows the bricks with completely new properties. This ceramic bond is based on the reduction and oxidation of MgO or Mg: Reduction: MgO + C ➞ Mg (g) + CO Reoxidation: 2 Mg (g) + O2 ➞ 2 MgO
The CERAMAC® brick stands out due to its unique combination of a flexible carbon bond with a stable ceramic bond. In the process, the bond matrix is graphitized, which has a positive impact on the mechanical properties and the oxidation behavior of the products. Thermal pre-treatment removes all of the volatile components from the bricks so that when they are pre-heated or used, no smoke or odors are released.
The CERAMAC® product line has undergone comprehensive testing and been tried in different standard applications, thus proving its benefits, which include service life increases of up to 10%.
Emission-free pre-heating as well as the increased service life make the CERAMAC® brick one of the most intelligent refractory solutions in steel production.
REFRALUMAX 87 exposed to alloy AA 7278* at: 800 °C
REFRALUMAX – The product series for primary and secondary aluminium production
REFRALUMAX 87 – The refractory brick for aluminium smelting furnaces
The low viscosity of liquid aluminium and the high corrosive potential of aluminium-based alloys demand a refractory brick with special properties. Anti-wetting additives are thus frequently used in order to improve durability of the refractory products. Up until now, however, standard additives have been unable to prevent an intense corrosion from occurring, in particular with aluminium-magnesium alloys. These additives tend to dissolve when faced with the not unusual temperatures of >1000 °C. Not only is the desired effect lost here but there is a risk of lasting damage to the brick structure from the decomposition products.
REFRALUMAX 87 exposed to alloy AA 7278* at: 1000 °C
REFRALUMAX 87 exposed to alloy AA 7278* at: 1200 °C
REFRALUMAX 25 after the cryolite test* at 950 °C *(> 60% cryolite, 40% sodium fluoride)
In order to solve this problem, Refratechnik has come up with its own innovative solution in the form of an anti-wetting system. This unique feature of REFRALUMAX 87 forms a protective layer on the hot face of the brick lining, protecting the wear lining against infiltration and corrosion. This new and patented system can withstand temperatures of up to 1200 °C.
REFRALUMAX 87 is a new kind of refractory brick which has been specially developed for use in secondary aluminium production. The brick has already proven its worth in various leading institutes over the world. Research organisations such as SINTEF and CIR have attested to its high level of corrosion resistance when in contact with liquid aluminium and aluminous alloys.
The high-quality aluminium refractory brick REFRALUMAX 87 is the first choice for the lining of aluminium smelting furnaces.
* > 85% Al; Si < 0.15%; Fe < 0.20%; Cu 1.7-2.1%; Mg 2.7-3.0%; Zn 6.8-7.2%;
REFRALUMAX 25 – The refractory brick for the reduction cell
The refractory lining of the base of electrolysis cells for primary aluminium production is subjected to major stress. Contact with the different salts and fluorides in particular requires a high-quality refractory product which is able to guarantee as high a durability as possible for the lining. Over the past few years, fireclay or aluminium silicate bricks have prevailed here.
The REFRALUMAX 25 is a refractory brick made from specially selected raw materials. Thanks to its low aluminium oxide content and optimised pore structure, the barrier brick boasts an excellent resistance to cryolite. The effects of infiltration and corrosion are minimised and superb heat resistance is guaranteed thanks to a vitreous, hot face barrier layer.
Of the end of the pitch era. REFRAFLEX® is a completely new innovation from the house of Refratechnik Steel. The first synthetic resin bonding that is better than pitch bonding, because it works without pitch. And it is better than a standard phenol synthetic resin bonding, as the carbon that is given off during coking does not become stiff and brittle, but crystaline like graphite, so that fireproof materials give, instead of equalizing stresses with macro cracks.
As a result, REFRAFLEX® offers all the advantages of pitch bonding while eliminating its main disadvantages: Because of the characteristic polycyclic aromats pitch is no longer tolerable in the steel industry.
For Refratechnik Steel it was important to meet the technical challenge and develop a process that combines the advantages of both bonding systems while eliminating their disadvantages. With REFRAFLEX® we have been successful.
The before and after effect: Classic resin bonding versus REFRAFLEX® bonding The following pictures show the macroscopic and structural differences between resin bonding and a REFRAFLEX® bond based on the same resin using macro pictures and scanning electron microscope pictures. For this, suitable samples were coked for six hours each at differing temperatures in the coking bed.
Even at the macroscopic level, the difference between the glass carbon shining like paint and the scaly, metallic shine of the graphite from the REFRALEX® bond can be recognized.
Through the heat treatment at 1500 °C spherical areas can be seen with the normal resin bonding next to amorphous phases, which indicate the beginning of the crystalization or vaporization processes. With the REFRAFLEX® bond on the other hand, these amorphous structures are no longer present. The lamellar layered structure of a well graphitized carbon is much more recognizable, which makes the refractory brick so flexible that it does not crack from stresses.
You can order the following Refratechnik brochures: Just click on the brochures in the language required, then fill in the contact form and submit it. We shall send you the requested information soonest.